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Updated: Aug 16, 2026

Unraveling Entropic Rate Acceleration Induced by Solvent Dynamics in Membrane Enzymes
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在可逆乙烯结合后,CuAlCl(4) 框架的吸收重建

Roger M Sullivan1, Haiming Liu, D Steve Smith

  • 1Department of Chemistry, North Carolina State University, Raleigh, North Carolina 27695-8204, USA.

Journal of the American Chemical Society
|September 4, 2003
PubMed
概括

铜化通过西格玛相互作用可逆吸附乙烯,形成新的晶体相. 这种烯酸结合机制是由晶格结构驱动的.

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The absorption of UV–visible light by conjugated systems causes the promotion of an electron from the ground state to the excited state. Consequently, photochemical electrocyclic reactions proceed via the excited-state HOMO rather than the ground-state HOMO. Since the ground- and excited-state HOMOs have different symmetries, the stereochemical outcome of electrocyclic reactions depends on the mode of activation; i.e., thermal or photochemical.
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