二氧化:一种来自正位置换的阿里和单片二氧化的过氧化物
David G Ho1, Ruomei Gao, Jeff Celaje
1Department of Chemistry and Biochemistry, California State University, Los Angeles, Los Angeles, CA 90032, USA.
概括
单片二氧化物与酸发生反应,形成氧化,将氧原子转移到酸中. 立体和电子因素影响这些关键中间体的稳定性.
科学领域:
- 有机化学 有机化学
- 氧化反应是一种氧化反应.
- 反应性中间体反应性中间体
背景情况:
- 阿里尔斯是有机合成中的多功能试剂.
- 单片二氧化物是一种高度反应性的氧物种.
- 了解单片二氧化碳与化合物的反应机制至关重要.
研究的目的:
- 为了研究单片二氧化碳与硬质阻碍的酸的反应.
- 为了描述由此产生的酸二氧化添加物.
- 为了探索二氧化的氧原子转移能力.
主要方法:
- 合成的三甲基) 啡.
- 与现场生成的单片氧气发生反应.
- 奥莱芬捕获实验.
- 在原始条件下反应中间体的表征.
主要成果:
- 形成一个稳定的phosphadioxirane添加物与tris(o-methoxyphenyl) .
- 证明非激进的氧原子转移到烯酸.
- 鉴定氧酸和氧酸的中间体.
- 酸氧化稳定性与酸的固体和电子特性之间的相关性.
结论:
- 单片氧气与酸的反应产生可分离的酸.
- 这些二氧化是有效的氧原子转移剂.
- 二氧化的稳定性是由酸的替代剂调节的.
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