碳洋的有机功能和光学特性
Vasilios Georgakilas1, Dirk M Guldi, Raffaella Signorini
1Dipartimento di Scienze Farmaceutiche, Università di Trieste, Piazzale Europa 1, 34127 Trieste, Italy.
Journal of the American Chemical Society
|November 20, 2003
概括
研究人员实现了碳洋的有机功能化,使其变得可溶和可净化. 这些功能化碳洋在可见和近红外区域都显示出出色的宽带光学限制特性.
科学领域:
- 材料科学 材料科学 材料科学
- 有机化学 有机化学
- 纳米技术 纳米技术
背景情况:
- 碳洋是一种碳纳米材料,通常在常见溶剂中不溶.
- 功能化是为特定应用量身定制纳米材料属性的关键.
研究的目的:
- 为了首次实现碳洋的有机功能化.
- 为了研究功能化碳洋的非线性光学特性,用于光学限制应用.
主要方法:
- 使用了1,3-二极旋转添加的亚甲化物.
- 功能化了无形碳和同心富勒烯的混合物.
- 从碳混合物中净化了功能化的碳洋.
主要成果:
- 成功实现了碳洋的有机功能化.
- 功能化的洋在有机溶剂中变得可溶,使其能够进行净化.
- 在可见和近红外区域展示了宽带光学限制能力.
结论:
- 有机功能化提供了一条可溶和可净化的碳洋的途径.
- 功能化的碳洋在光学限制器应用中表现出有前途的非线性光学特性.
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