Jove
Visualize
联系我们
JoVE
x logofacebook logolinkedin logoyoutube logo
关于 JoVE
概览领导团队博客JoVE 帮助中心
作者
出版流程编辑委员会范围与政策同行评审常见问题投稿
图书馆员
用户评价订阅访问资源图书馆顾问委员会常见问题
研究
JoVE JournalMethods CollectionsJoVE Encyclopedia of Experiments存档
教育
JoVE CoreJoVE BusinessJoVE Science EducationJoVE Lab Manual教师资源中心教师网站
使用条款与条件
隐私政策
政策

相关概念视频

Cooperative Allosteric Transitions01:58

Cooperative Allosteric Transitions

Cooperative allosteric transitions can occur in multimeric proteins, where each subunit of the protein has its own ligand-binding site. When a ligand binds to any of these subunits, it triggers a conformational change that affects the binding sites in the other subunits; this can change the affinity of the other sites for their respective ligands. The ability of the protein to change the shape of its binding site is attributed to the presence of a mix of flexible and stable segments in the...
Thermal and Photochemical Electrocyclic Reactions: Overview01:26

Thermal and Photochemical Electrocyclic Reactions: Overview

Electrocyclic reactions are reversible reactions. They involve an intramolecular cyclization or ring-opening of a conjugated polyene. Shown below are two examples of electrocyclic reactions. In the first reaction, the formation of the cyclic product is favored. In contrast, in the second reaction, ring-opening is favored due to the high ring strain associated with cyclobutene formation.
Photochemical Electrocyclic Reactions: Stereochemistry01:26

Photochemical Electrocyclic Reactions: Stereochemistry

The absorption of UV–visible light by conjugated systems causes the promotion of an electron from the ground state to the excited state. Consequently, photochemical electrocyclic reactions proceed via the excited-state HOMO rather than the ground-state HOMO. Since the ground- and excited-state HOMOs have different symmetries, the stereochemical outcome of electrocyclic reactions depends on the mode of activation; i.e., thermal or photochemical.
Selection Rules: Photochemical Activation
Ion Exchange01:17

Ion Exchange

Ion exchange chromatography separates charged molecules from a solution by reversibly exchanging them with mobile, or 'active', ions associated with the oppositely charged stationary phase. This method can be used to separate ions, soften and deionize water, and purify solutions. The polymers comprising the ion-exchange column are high-molecular-weight and chemically stable polymers, crosslinked to be porous and essentially insoluble. They are also functionalized with either acidic or basic...
Types of Reversible Electrodes01:24

Types of Reversible Electrodes

For electrode reversibility to be maintained, all the reactants and products involved in the half-reaction must be present at the electrode. There are several types of reversible electrodes (half-cells).In metal-metal-ion electrodes, a metal balances electrochemically with a solution of its own ions. Examples are Cu2+|Cu and Zn2+|Zn. Metals that react with the solvent, like group 1 and most group 2 metals, which react with water, and zinc, which reacts with aqueous acidic solutions, cannot be...
The Electrical Double Layer01:30

The Electrical Double Layer

In the region where two bulk phases meet, an intricate electric charge distribution arises due to charge transfer, ion adsorption, molecular orientation, and charge distortion. This complex distribution is commonly referred to as the electrical double layer.When a solid electrode interfaces with ions in an electrolyte solution, the speed of electron transfer dictates the rates of oxidation and reduction. The electrode acquires a charge through the escape of atoms into the solution as cations or...

您也可能阅读

相关文章

通过共同作者、期刊和引用图与本文相关的文章。

排序
Same author

A synergistic dual-endopeptidase platform for high-yield, homogeneous F(ab')<sub>2</sub> production from polyclonal equine immunoglobulins for therapeutic applications.

Journal of chromatography. B, Analytical technologies in the biomedical and life sciences·2026
Same author

A Short History of the Institute for Polymers and Organic Solids (IPOS) at UCSB.

ACS applied materials & interfaces·2026
Same author

Immunohistochemical determination of the expression of Eph receptors in lipid-rich variation of experimental rat mammary carcinomas.

Journal of molecular histology·2025
Same author

Immunoaffinity chromatography for the preparation of equine tetanus immunoglobulin F(ab')<sub>2</sub> for enhanced safety and efficacy.

Journal of chromatography. B, Analytical technologies in the biomedical and life sciences·2025
Same author

Severe degranulation of mesenteric mast cells in an experimental rat mammary tumor model.

Turkish journal of medical sciences·2024
Same author

A Toast to Maurizio Prato.

Chemistry (Weinheim an der Bergstrasse, Germany)·2023

相关实验视频

Updated: Jul 6, 2026

Production and Characterization of Vacuum Deposited Organic Light Emitting Diodes
07:44

Production and Characterization of Vacuum Deposited Organic Light Emitting Diodes

Published on: November 16, 2018

新型可逆离子-共价转换在高导电性TFT衍生物中的新型可逆离子-共价转换.

Clifton Kwang-Fu Shen1, Hieu M Duong, Gursel Sonmez

  • 1Department of Chemistry and Biochemistry and Exotic Materials Institute, University of California at Los Angeles, Los Angeles, California 90095-1569, USA.

Journal of the American Chemical Society
|December 25, 2003
PubMed
概括

甲 (TTF) 与甲异构体的相互作用产生了不同的结果. 同体形成一个绝缘固体,而正体同体创造了一个独特的系统,具有可互换的导电元件.

科学领域:

  • 固态化学 固态化学
  • 有机电子学有机电子学

背景情况:

  • 甲 (TTF) 是一种众所周知的电子捐赠体,用于有机导体.
  • 甲以para和ortho异构体的形式存在,可能会影响TTF复杂性质.

研究的目的:

  • 为了研究由TTF与para-和ortho-chloranil异构体相互作用而产生的固态现象.
  • 描述由此产生的电荷转移复合体的结构和电子特性.

主要方法:

  • TTF-chloranil复合物的合成和表征.
  • 进行X射线衍射分析以确定晶体结构.
  • 电导率测量. 电导率测量. 电导率测量. 电导率测量. 电导率测量.

主要成果:

  • 在环境温度下,TTF与para-chloranil形成一个绝缘,交替堆与中性元件.
  • 与正方体烯结合的TTF形成了一个表现出可相互转换的导电离子和共价元件的系统.
  • 异构体差异显著影响电荷转移复杂性质.

结论:

  • 甲的特定异构体决定了与TTF复合时产生的固态特性.
  • орто-chloranil为具有可调电子状态的新型导电材料提供了一条途径.

更多相关视频

An Electrochemical Cholesteric Liquid Crystalline Device for Quick and Low-Voltage Color Modulation
10:33

An Electrochemical Cholesteric Liquid Crystalline Device for Quick and Low-Voltage Color Modulation

Published on: February 27, 2019

Development of Efficient OLEDs from Solution Deposition
07:09

Development of Efficient OLEDs from Solution Deposition

Published on: November 4, 2022

相关实验视频

Last Updated: Jul 6, 2026

Production and Characterization of Vacuum Deposited Organic Light Emitting Diodes
07:44

Production and Characterization of Vacuum Deposited Organic Light Emitting Diodes

Published on: November 16, 2018

An Electrochemical Cholesteric Liquid Crystalline Device for Quick and Low-Voltage Color Modulation
10:33

An Electrochemical Cholesteric Liquid Crystalline Device for Quick and Low-Voltage Color Modulation

Published on: February 27, 2019

Development of Efficient OLEDs from Solution Deposition
07:09

Development of Efficient OLEDs from Solution Deposition

Published on: November 4, 2022