一个新的 (II) 蒸发色盐类别
Levi J Grove1, Jeffrey M Rennekamp, Hershel Jude
1University of Cincinnati, Department of Chemistry, P.O. Box 210172, Cincinnati, Ohio 45221-0172, USA.
Journal of the American Chemical Society
|February 12, 2004
概括
新的化合物在暴露于挥发性有机化合物时表现出蒸发色,改变颜色和排放. 这种可逆的颜色变化表明了传感应用的潜力.
科学领域:
- 无机化学 无机化学 有机化学
- 材料科学 材料科学 材料科学
- 摄影化学的使用.
背景情况:
- 复合体因其独特的光物理性质而受到探索.
- 蒸气色变,即暴露在蒸气中的光学特性变化,是传感器开发的理想特征.
研究的目的:
- 为了合成和表征新的发光盐.
- 为了研究这些盐在对挥发性有机化合物 (VOC) 的反应中表现出的蒸发色行为.
主要方法:
- 合成发光化物和Pt(Me2bzimpy) Cl+ 的六酸盐.
- 用各种VOC进行固态蒸汽暴露实验.
- 紫外线可见吸收和发射光谱 (室温和77K) 用于分析光谱变化.
主要成果:
- 化物和六酸盐都表现出蒸发色,显示可逆的颜色和排放变化.
- 化盐对甲醇,,乙醇和酸乙烯反应,从黄色变为红色.
- 六酸盐选择性地对乙二反应,从黄色变为紫色.
结论:
- 观察到的蒸发色与固态内- (Pt...Pt) 分离的变化有关.
- 这些化合物显示出作为检测挥发性有机化合物的响应材料的潜力.
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