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Updated: Aug 12, 2026

Self-assembling Morphologies Obtained from Helical Polycarbodiimide Copolymers and Their Triazole Derivatives
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Published on: February 7, 2017

通过Cy3PCuMe和 (Bipy) 2FeEt2Fe2Et2进行烯二烯聚合

Frank Schaper1, Stephen R Foley, Richard F Jordan

  • 1Department of Chemistry, The University of Chicago, 5735 S. Ellis Avenue, Chicago, Illinois 60637, USA.

Journal of the American Chemical Society
|February 20, 2004
PubMed
概括

在低温下,PCuMe经历可逆的连接物再分配,形成离子对. 这种复合物与自由三环基啡 (PCy(3) 一起,通过阴离子机制启动了烯烯聚合.

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Acyclic diene metathesis polymerization or ADMET polymerization involves cross-metathesis of terminal dienes, such as 1,8-nonadiene, to give linear unsaturated polymer and ethylene. As ADMET is a reversible process, the formed ethylene gas must be removed from the reaction mixture to complete the polymerization process.
Similar to cross-metathesis, ADMET also involves the formation of metallacyclobutane intermediate by [2+2] cycloaddition of one of the double bonds of a terminal diene with...