超分子树突性液体半晶体 超分子树突性液体半晶体
Xiangbing Zeng1, Goran Ungar, Yongsong Liu
1Department of Engineering Materials, University of Sheffield, Sheffield S1 3JD, UK.
Nature
|March 12, 2004
概括
软物质自组织成有序的阶段. 研究人员发现准周期性结构,类似于金属合金中的准晶体,可以在缩放的微粒阶段形成,揭示了一个新的组织原理.
科学领域:
- 软物质物理学 软物质物理学
- 材料科学 材料科学 材料科学
- 晶体学 晶体学是指结晶学.
背景情况:
- 合成和天然化合物自组织成纳米级周期的散体相.
- 这些有序相,包括状,柱状和状结构,通常遵循晶体学规则.
- 一些金属合金表现出准晶体,挑战了传统的晶体对称性.
研究的目的:
- 为了研究半周期性结构,类似于准晶体,是否可以在软物质系统中出现.
- 在自组装阶段探索超越传统晶体学组织的新模式.
主要方法:
- 分析光热和热热系统中自我组织的散装相.
- 软物质结构中的对称规则与金属合金中的对称规则的比较.
- 在扩大规模的菌根阶段中识别和描述准周期秩序.
主要成果:
- 软物质的自我组装导致周期性结构 (1D,2D,3D) 服从晶体对称.
- 软物质中的状相与特定金属合金的结晶学对应物共享.
- 准周期性结构,以前只在准晶体中观察到,已被证明存在于软物质的细胞阶段.
结论:
- 软物质可以表现出准周期性组织,扩大了对自组装的理解,超越了传统的晶体学.
- 在软物质中发现准晶体,为设计具有独特性质的材料开辟了新的途径.
- 这一发现代表了软物质领域的新型组织模式.
相关概念视频
Structures of Solids
Solids in which the atoms, ions, or molecules are arranged in a definite repeating pattern are known as crystalline solids. Metals and ionic compounds typically form ordered, crystalline solids. A crystalline solid has a precise melting temperature because each atom or molecule of the same type is held in place with the same forces or energy. Amorphous solids or non-crystalline solids (or, sometimes, glasses) which lack an ordered internal structure and are randomly arranged. Substances that...
Molecular and Ionic Solids
Crystalline solids are divided into four types: molecular, ionic, metallic, and covalent network based on the type of constituent units and their interparticle interactions.
Molecular Solids
Molecular crystalline solids, such as ice, sucrose (table sugar), and iodine, are solids that are composed of neutral molecules as their constituent units. These molecules are held together by weak intermolecular forces such as London dispersion forces, dipole-dipole interactions, or hydrogen bonds, which...
Molecular Solids
Molecular crystalline solids, such as ice, sucrose (table sugar), and iodine, are solids that are composed of neutral molecules as their constituent units. These molecules are held together by weak intermolecular forces such as London dispersion forces, dipole-dipole interactions, or hydrogen bonds, which...
Ionic Crystal Structures
Ionic crystals consist of two or more different kinds of ions that usually have different sizes. The packing of these ions into a crystal structure is more complex than the packing of metal atoms that are the same size.
Most monatomic ions behave as charged spheres, and their attraction for ions of opposite charge is the same in every direction. Consequently, stable structures for ionic compounds result (1) when ions of one charge are surrounded by as many ions as possible of the opposite...
Most monatomic ions behave as charged spheres, and their attraction for ions of opposite charge is the same in every direction. Consequently, stable structures for ionic compounds result (1) when ions of one charge are surrounded by as many ions as possible of the opposite...
Network Covalent Solids
Network covalent solids contain a three-dimensional network of covalently bonded atoms as found in the crystal structures of nonmetals like diamond, graphite, silicon, and some covalent compounds, such as silicon dioxide (sand) and silicon carbide (carborundum, the abrasive on sandpaper). Many minerals have networks of covalent bonds.
To break or to melt a covalent network solid, covalent bonds must be broken. Because covalent bonds are relatively strong, covalent network solids are typically...
To break or to melt a covalent network solid, covalent bonds must be broken. Because covalent bonds are relatively strong, covalent network solids are typically...
Recrystallization: Solid–Solution Equilibria
Recrystallization is a purification technique used to separate impurities from solid compounds. In this technique, no chemical reactions occur. Instead, it exploits physical properties only, specifically, the solubility differences between the desired compound and impurities, either at a single temperature or at different temperatures, and under other selected conditions. The solid-solution equilibrium (solubility equilibrium) of each component in the solution represents a binary phase...
Liquid–Solid Solutions
The process of a solid dissolving in a liquid to form a solution is governed by the solubility limit, which is the maximum amount of the solid substance, or solute, that can be dissolved in a specific volume of the liquid or solvent. As the solute dissolves, it reaches a point where no more solute can be dissolved at a given temperature - this is known as the saturation point. However, if further solute is added and it manages to dissolve, the solution becomes supersaturated. Supersaturated...


