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In situ TEM of Biological Assemblies in Liquid
Published on: December 30, 2013
液晶章鱼树状体:具有不寻常的中相形态的块分子
Lionel Gehringer1, Cyril Bourgogne, Daniel Guillon
1Institut de Physique et Chimie des Matériaux de Strasbourg - IPCMS, Groupe des Matériaux Organiques - GMO, UMR 7504 - CNRS/Université Louis Pasteur, 23, rue du Loess, BP 43, F-67034 Strasbourg Cedex 2, France.
Journal of the American Chemical Society
|March 25, 2004
概括
具有独特的分支结构的新型章鱼树状树体表现出新的液晶相. 它们的中相行为取决于分子架构,为先进材料提供了对结构属性关系的见解.
科学领域:
- 材料科学 材料科学 材料科学
- 有机化学 有机化学
- 聚合物科学 聚合物科学
背景情况:
- 经典的液晶树状体通常具有终端功能.
- 之前的工作集中在具有相同构建块的同质树突系统上.
研究的目的:
- 合成和描述新的主链液晶树状体,称为章鱼树状体.
- 为了研究这些新型树突系统,特别是异质石系统的中形性质.
主要方法:
- 树突分支和树枝的模块化合成.
- 极化光学显微镜. 极化光学显微镜.
- X射线衍射研究 (包括小布拉格角).
- 分子模式化. 分子模式化.
主要成果:
- 成功合成了具有独特树叶的新型异质石章鱼树状体.
- 观察具有新型形态的状和柱状液晶相.
- 半位相类型和稳定性取决于终端链和半位相段的数量和排列.
结论:
- 与古典系统相比,章鱼树状体表现出明显的中形性质.
- 分子架构,包括 mesogenic 段的性质和空间位置,极大地影响 mesophase 行为.
- 拟议的模型用于分子组织在 smectic 和柱状阶段.
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