实验证据表明,在地球下层地幔中存在富含铁的金属
Daniel J Frost1, Christian Liebske, Falko Langenhorst
1Bayerisches Geoinstitut, University of Bayreuth, D-95440 Bayreuth, Germany. dan.frost@uni-bayreuth.de
Nature
|March 26, 2004
概括
下层地幔含有大量的铁 (Fe3+),独立于氧气水平. 这一发现表明下层地幔具有明显的氧化状态,并且可能含有富含铁的金属合金.
科学领域:
- 地质化学 地质化学
- 矿物物理 矿物物理
- 地球科学 地球科学 地球科学
背景情况:
- 地幔氧化状态对于理解行星进化至关重要.
- 矿物中的Fe3+/Fe2+比率记录了氧化还原条件.
- 矿物Fe3+的纳入能力影响了地幔的氧化还原状态.
研究的目的:
- 调查下层地幔酸盐矿中的Fe3+含量.
- 确定氧气流动性对矿Fe3+的影响.
- 评估下层地幔氧化状态和组成的影响.
主要方法:
- 高压实验测量. 高压实验测量.
- 在酸矿中Fe3+和Fe2+分布的分析.
- 用金属铁进行平衡实验.
主要成果:
- 类酸盐矿Fe3+含量独立于氧气流动性.
- 高Fe3+水平存在于矿中,即使与金属铁处于平衡状态.
- 下地幔矿具有Fe3+/总Fe比率至少为0.6.6.
结论:
- 下层地幔的Fe3+比重明显高于上层地幔.
- 下层地幔可能含有~1重%的金属富含铁合金.
- 这种合金影响地幔氧化状态和 siderophile 元素预算.
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