六角双金字塔形红宝石晶体的流体生长
Shuji Oishi1, Katsuya Teshima, Hitoshi Kondo
1Department of Environmental Science and Technology, Faculty of Engineering, Shinshu University, Nagano 380-8553, Japan. oishish@gipwc.shinshu-u.ac.jp
Journal of the American Chemical Society
|April 15, 2004
概括
研究人员使用三氧化流体轻松生长了六边形双金字塔形红宝石晶体. 这种方法产生了透明的红色晶体,面部发育良好,显示MoO3.
科学领域:
- 材料科学 材料科学 材料科学
- 晶体学 晶体学是指结晶学.
- 固态化学 固态化学
背景情况:
- 红宝石 (Al2O3:Cr) 是一种有价值的宝石和激光材料.
- 晶体生长方法对于获得高质量的红宝石晶体至关重要.
- 流体生长为合成氧化物晶体提供了一个可行的途径.
研究的目的:
- 为了研究生长六角形双金字塔形红宝石晶体的可行性.
- 评估三氧化物 (MoO3) 作为红宝石晶体生长的流量.
- 描述合成的红宝石晶体的形态和特性.
主要方法:
- 通过同热蒸发MoO3流量的结晶生长.
- 在1100°C加热氧化 (Al2O3),氧化 (Cr2O3) 和MoO3流的混合物5小时.
- 晶体形态和尺寸的表征.
主要成果:
- 成功地生长了六角形双金字塔形红宝石晶体.
- 晶体呈现出透明红色的颜色.
- 获得的晶体长度高达1.8mm,宽度高达1.7mm.
- 在双金字塔晶体上识别出发达的面孔.
- 三氧化物被证明是这种生长的合适流体.
结论:
- 对MoO3流的同热蒸发是一种有效的方法,用于生长六边形双金字塔形红宝石晶体.
- 113面是这种条件下生长的红宝石晶体的特征.
- MoO3是合成高质量的红宝石晶体的一个有前途的流体.
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