在森林中缺少OH反应性:证据表明存在未知的活性生物原体VOCs
Piero Di Carlo1, William H Brune, Monica Martinez
1Department of Meteorology, Pennsylvania State University, University Park, PA 16802, USA. piero.dicarlo@aquila.infn.it
概括
生物源性挥发性有机化合物 (BVOC) 的森林排放有助于臭氧和气溶. 未知反应性BVOC,可能是烯,解释了密歇根州森林研究中观察到的高于预期的OH反应性.
科学领域:
- 大气化学 大气化学
- 森林生态 森林生态
- 环境科学 环境科学
背景情况:
- 来自森林的生物性挥发性有机化合物 (BVOC),包括异烯和烯,影响大气化学.
- 热带层臭氧和气溶的形成受到森林排放的影响.
- OH反应性是大气氧化过程的关键指标.
研究的目的:
- 调查密歇根州北部森林中测量和预期的OH总反应率之间的差异.
- 为了确定未测量的OH反应性的潜在来源.
- 测试假设未知反应性BVOCs有助于缺少OH反应性的假设.
主要方法:
- 在森林环境中直接测量总OH反应性.
- 量化BVOC排放率,包括烯.
- 分析温度,BVOC排放和OH反应性之间的关系.
主要成果:
- 测量到的总OH反应性明显高于基于已知化合物的预测.
- "缺失"的OH反应性随着环境温度的增加而增加.
- 烯和其他BVOC的排放率也随着温度的增加而增加.
结论:
- 未知反应性BVOC可能是观察到的"缺失"OH反应性的原因.
- 烯是这些未知反应性化合物的潜在候选物.
- 森林排放在大气化学中起着至关重要的,而且可能被低估的作用.
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