诱导的功能化bis () 的非线性光学性能的切换
Graziano Fabbrini1, Enzo Menna, Michele Maggini
1Dipartimento di Scienze Chimiche and ITM-CNR, Università di Padova, Via Marzolo, 1 I-35131 Padova, Italy.
Journal of the American Chemical Society
|May 20, 2004
概括
在结合时,基于环的分子的吸收光谱的小变化会显著改变其非线性传输. 这可以通过一个连续的两光子吸收过程来解释.
科学领域:
- 摄影化学的使用.
- 材料科学 材料科学 材料科学
- 超分子化学 超分子化学
背景情况:
- 非线性光学特性对于先进的光子应用至关重要.
- 基于环的分子提供可调节的电子和光物理特性.
- 金属离子结合可以调节分子性质,但在非线性传输中并不总是观察到很大的变化.
研究的目的:
- 为了研究Zn2+结合对基于环的基的非线性传播的影响.
- 了解对观察到的变化负责的潜在光物理机制.
- 探索开发响应式光学材料的潜力.
主要方法:
- 一种基于环的二 () 乙衍生物的合成.
- 谱分析 (UV-Vis吸收) 用于研究Zn2+结合.
- 测量非线性传输以评估光学性能.
- 基于光物理模型的理论解释.
主要成果:
- 在Zn2+协调时,线性吸收光谱的轻微变化.
- 观察到非线性传输属性的显著,很大的变化.
- 实验数据与一个连续的两光子吸收机制保持一致.
结论:
- 结合Zn2+与环部分会导致非线性光学行为的实质性变化.
- 观察到的非线性传输是由一个连续的两光子过程控制的.
- 这项工作展示了设计金属离子响应的非线性光学材料的策略.
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