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两个阶段的分散聚合,以单分散,受控的微米大小的共聚合物颗粒
Jing-She Song1, Frédéric Tronc, Mitchell A Winnik
1Department of Chemistry, University of Toronto, 80 St. George Street, Toronto, Ontario, Canada M5S 3H6.
Journal of the American Chemical Society
|May 27, 2004
概括
一种新的两阶段分散聚合法精确控制微米大小的聚合物颗粒合成. 这种技术允许在不影响颗粒大小或分布的情况下加入功能性单体和交叉连接器.
科学领域:
- 聚合物化学 聚合物化学
- 材料科学 材料科学 材料科学
- 纳米技术纳米技术
背景情况:
- 分散聚合是一种合成聚合物颗粒的关键技术.
- 结合功能性单体和交叉连接剂往往导致对粒子大小和分布的控制较差.
研究的目的:
- 开发一种强大的两阶段分散聚合法.
- 为了使单分散,功能化和交叉连接的聚合物颗粒在受控尺寸的合成.
主要方法:
- 采用了两阶段的分散聚合过程.
- 功能性单体和交叉链接剂是在核化后添加的.
- 在第二阶段添加单体,控制最终粒子直径.
主要成果:
- 单分散微米大小的聚合物颗粒已成功制备.
- 功能性单体和交叉连接剂被纳入,而不会破坏颗粒大小或分布.
- 实现了对粒子直径的精确控制和产生交联粒子 (高达3mol%) 的能力.
结论:
- 开发的两阶段方法为聚合物颗粒合成提供了更好的控制.
- 这一策略有助于创建适合各种应用的定制聚合物颗粒.
- 该工艺适用于生产含有染料标记或功能组的颗粒.
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