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Updated: Jul 16, 2026

Photopatterning Proteins and Cells in Aqueous Environment Using TiO2 Photocatalysis
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在水热条件下的TiCl3水溶液中,分微米尺度的矩形平行管状鲁基TiO2薄膜的生长

Eiji Hosono1, Shinobu Fujihara, Keita Kakiuchi

  • 1Department of Applied Chemistry, Faculty of Science and Technology, Keio University, Yokohama 223-8522, Japan.

Journal of the American Chemical Society
|June 24, 2004
PubMed
概括

用化处理 (III) 化溶液的热水处理产生了新型的鲁二氧化 (TiO2) 薄膜. 这些片展示了近乎单晶的平行平动物的独特形态.

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Radical substitution reactions can be used to remove functional groups from molecules. The hydrogenolysis of alkyl halides is one such reaction, where the weak Sn–H bond in tributyltin hydride reacts with alkyl halides to form alkanes. Here, the reagent Bu3SnH yields tributyltin halide as a byproduct.
The bonds formed in this reaction are stronger than the bonds broken, making it energetically favorable. The reaction follows a radical chain mechanism similar to radical halogenation reactions,...