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All-electronic Nanosecond-resolved Scanning Tunneling Microscopy: Facilitating the Investigation of Single Dopant Charge Dynamics
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从铁(II) -tris[2,2'-bi(tetrahydropyrimidine) ]到TEMPO的原子转移:由马库斯方程预测的负度的激活

Elizabeth A Mader1, Anna S Larsen, James M Mayer

  • 1Department of Chemistry, University of Washington, Box 351700, Seattle, Washington 98195-1700.

Journal of the American Chemical Society
|July 1, 2004
PubMed
概括

研究了铁复合体和TEMPO之间的质子合电子转移 (PCET). 该反应表现出异常的负激活度,支持马库斯理论对原子转移反应的预测.

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