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相关概念视频

Solvents01:12

Solvents

A solvent is a substance, most often a liquid, that can dissolve other substances. Here, the substance being dissolved is called a solute. When a solvent and a solute combine, they form a solution - a homogenous mixture of both the solvent and the solute. Water is a universal biological solvent. Its polar structure allows it to dissolve many other polar compounds. The ability of water to dissolve is governed by a balance between water molecules binding to each other and binding to the solute.
A...
What are Carbohydrates?01:44

What are Carbohydrates?

Overview
Solubility of Ionic Compounds02:55

Solubility of Ionic Compounds

Solubility is the measure of the maximum amount of solute that can be dissolved in a given quantity of solvent at a given temperature and pressure. Solubility is usually measured in molarity (M) or moles per liter (mol/L). A compound is termed soluble if it dissolves in water.
Precipitation Reactions03:10

Precipitation Reactions

In a precipitation reaction, aqueous solutions of soluble salts react to give an insoluble ionic compound – the precipitate. The reaction occurs when oppositely charged ions in solution overcome their attraction for water and bind to each other, forming a precipitate that separates out from the solution. Since such reactions involve the exchange of ions between ionic compounds in aqueous solution, they are also referred to as double displacement, double replacement, exchange reactions, or...
Solution Equilibrium and Saturation01:59

Solution Equilibrium and Saturation

Imagine adding a small amount of sugar to a glass of water, stirring until all the sugar has dissolved, and then adding a bit more. You can repeat this process until the sugar concentration of the solution reaches its natural limit, a limit determined primarily by the relative strengths of the solute-solute, solute-solvent, and solvent-solvent attractive forces. You can be certain that you have reached this limit because, no matter how long you stir the solution, undissolved sugar remains. The...
Factors Affecting Solubility04:01

Factors Affecting Solubility

Compared with pure water, the solubility of an ionic compound is less in aqueous solutions containing a common ion (one also produced by dissolution of the ionic compound). This is an example of a phenomenon known as the common ion effect, which is a consequence of the law of mass action that may be explained using Le Chȃtelier’s principle. Consider the dissolution of silver iodide:

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相关实验视频

Updated: Jul 13, 2026

Metabolic Glycoengineering of Sialic Acid Using N-acyl-modified Mannosamines
12:06

Metabolic Glycoengineering of Sialic Acid Using N-acyl-modified Mannosamines

Published on: November 25, 2017

在水溶液中的糖的酸盐复合物.

Joseph B Lambert1, Gang Lu, Stephanie R Singer

  • 1Department of Chemistry, Northwestern University, 2145 Sheridan Road, Evanston, Illinois 60208, USA. jlambert@northwestern.edu

Journal of the American Chemical Society
|August 5, 2004
PubMed
概括

某些糖类与酸形成可溶性酸复合物,但只有特定的花粉素形式反应. 这种选择性反应涉及无分子基组,对前生物化学有影响.

科学领域:

  • 碳水化合物化学 碳水化合物化学
  • 酸盐化学 酸盐化学
  • 益生菌化学 益生菌化学

背景情况:

  • 糖可以与酸反应,形成可溶性酸复合物.
  • 糖的结构及其配置对于复杂的形成至关重要.

研究的目的:

  • 调查糖-酸复合体形成的结构要求.
  • 了解这种反应的选择性及其潜在影响.

主要方法:

  • 核磁共振 (NMR) 谱学,特别是 (29) Si 和 (13) C NMR,用于分析产品.
  • 研究了各种单糖和分糖与基本酸的反应.

主要成果:

  • 只有糖的 furanose 形式与酸反应,形成 2/1 (糖/酸) 酸盐.
  • 反应需要异构基组与相邻的基组相结合.
  • 特定的糖类如核糖,糖和果糖形成复合物,而葡萄糖和银河糖则没有.

结论:

  • 糖酸盐复合物的形成高度选择性,取决于糖的结构和基组的配置.
  • 反应机制涉及通过五个成员的二氧化环进行化.
  • 这种选择性可能在 prebiotic 化学过程中发挥作用.

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