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在溶液中的烯 (VI) -烯 (V) 复合体中进行电子转移

Timofei Privalov1, Peter Macak, Bernd Schimmelpfennig

  • 1Department of Chemistry, Organic and Inorganic Chemistry, The Royal Institute of Technology, S-10044 Stockholm, Sweden.

Journal of the American Chemical Society
|August 5, 2004
PubMed
概括

量子化学方法揭示了 (V) 和 (VI) 在溶液中的电子自我交换率. 与外层水离子相比,内部球体的机制显著加快了电子转移.

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