热诱导的原子Au集群的形成和转化为纳米立方体
Rongchao Jin1, Shunji Egusa, Norbert F Scherer
1Department of Chemistry, James Franck Institute, and Consortium for Nanoscience Research, University of Chicago, 5735 South Ellis Avenue, Chicago, Illinois 60637, USA.
Journal of the American Chemical Society
|August 12, 2004
概括
这项研究介绍了一种热方法,将金合物转化为金色修剪器,即原子金. 这些稳定的黄金修剪器可以用来种植黄金纳米立方体.
科学领域:
- 材料科学 材料科学 材料科学
- 纳米技术 纳米技术
- 物理化学 物理化学
背景情况:
- 合金纳米颗粒广泛用于各种应用.
- 控制金纳米材料的尺寸和结构对于调整它们的特性至关重要.
- 原子集群提供独特的特性,与较大的纳米粒子有所区别.
研究的目的:
- 开发一种用于将金合物转化为原子金的热方法.
- 为了描述由此产生的黄金集群.
- 调查这些星团中黄金纳米立方体的后续生长.
主要方法:
- 热转化金合物. 热转化金合物.
- 用于集群识别的质谱分析.
- 光学吸收光谱学用于表征.
- 金纳米立方体的受控生长.
主要成果:
- 成功地将金合物转化为原子金.
- 通过质谱学识别了集群作为金色修剪器 (Au3).
- 在305nm和250nm观察到金色修剪器的明显的光学吸收峰值.
- 在环境条件下证明了金色修剪器在环境条件下的非凡稳定性.
- 展示了黄金纳米立方体从黄金trimers的后续增长.
结论:
- 一种新的热法使得从黄金合物中合成稳定的黄金trimers成为可能.
- 金色修饰器具有独特的光学特性和显著的稳定性.
- 合成的黄金修剪器作为黄金纳米立方体制造的有效前体.
相关概念视频
Atomic Structure
All matter is composed of atoms, the smallest individual units of elements. Each atom is made up of three subatomic particles: protons, neutrons, and electrons. Together, these three particles account for the mass and the charge of an atom.The History of Atomic TheoryThe first person to propose that everything on Earth is made up of tiny particles was the Greek philosopher Democritus, around 450 B.C. He used the term atomos, Greek for “indivisible,” from which the modern term “atom” is derived.
Subatomic Particles
Dalton was only partially correct about the particles that make up matter. All matter is composed of atoms, and atoms are composed of three smaller subatomic particles: protons, neutrons, and electrons. These three particles account for the mass and the charge of an atom.
Nuclear Transmutation
Nuclear transmutation is the conversion of one nuclide into another. It can occur by the radioactive decay of a nucleus, or the reaction of a nucleus with another particle. The first manmade nucleus was produced in Ernest Rutherford’s laboratory in 1919 by a transmutation reaction, the bombardment of one type of nuclei with other nuclei or with neutrons. Rutherford bombarded nitrogen-14 atoms with high-speed α particles from a natural radioactive isotope of radium and observed protons being...


