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Updated: Aug 22, 2026

Preparation of a Corannulene-functionalized Hexahelicene by Copper(I)-catalyzed Alkyne-azide Cycloaddition of Nonplanar Polyaromatic Units
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Preparation of a Corannulene-functionalized Hexahelicene by Copper(I)-catalyzed Alkyne-azide Cycloaddition of Nonplanar Polyaromatic Units

Published on: September 18, 2016

高度选择性和简单的合成C(2)(m) -X-C(2)(n) 富勒二元体

Yuliang Zhao1, Zhenling Chen, Hui Yuan

  • 1Institute of High Energy Physics, Chinese Academy of Science, Beijing 100039, China. zhaoyuliang@ihep.ac.cn

Journal of the American Chemical Society
|September 10, 2004
PubMed
概括

能量辐射可以通过创建共价键来选择性合成富勒烯二元体 (C2m-X-C2n). 这种多功能方法产生了新的富勒分子,并为富勒聚合物科学提供了一种新的方法.

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The Diels–Alder reaction is an example of a thermal pericyclic reaction between a conjugated diene and an alkene or alkyne, commonly referred to as a dienophile. The reaction involves a concerted movement of six π electrons, four from the diene and two from the dienophile, forming an unsaturated six-membered ring. As a result, these reactions are classified as [4+2] cycloadditions.
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Cycloadditions are one of the most valuable and effective synthesis routes to form cyclic compounds. These are concerted pericyclic reactions between two unsaturated compounds resulting in a cyclic product with two new σ bonds formed at the expense of π bonds. The [4 + 2] cycloaddition, known as the Diels–Alder reaction, is the most common. The other example is a [2 + 2] cycloaddition.
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