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相关概念视频

Batteries and Fuel Cells03:12

Batteries and Fuel Cells

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A battery is a galvanic cell that is used as a source of electrical power for specific applications. Modern batteries exist in a multitude of forms to accommodate various applications, from tiny button batteries such as those that power wristwatches to the very large batteries used to supply backup energy to municipal power grids. Some batteries are designed for single-use applications and cannot be recharged (primary cells), while others are based on conveniently reversible cell reactions that...
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Structures of Solids02:22

Structures of Solids

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Solids in which the atoms, ions, or molecules are arranged in a definite repeating pattern are known as crystalline solids. Metals and ionic compounds typically form ordered, crystalline solids. A crystalline solid has a precise melting temperature because each atom or molecule of the same type is held in place with the same forces or energy. Amorphous solids or non-crystalline solids (or, sometimes, glasses) which lack an ordered internal structure and are randomly arranged. Substances that...
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Molecular and Ionic Solids02:54

Molecular and Ionic Solids

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Crystalline solids are divided into four types: molecular, ionic, metallic, and covalent network based on the type of constituent units and their interparticle interactions.
Molecular Solids
Molecular crystalline solids, such as ice, sucrose (table sugar), and iodine, are solids that are composed of neutral molecules as their constituent units. These molecules are held together by weak intermolecular forces such as London dispersion forces, dipole-dipole interactions, or hydrogen bonds, which...
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Metallic Solids02:37

Metallic Solids

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Metallic solids such as crystals of copper, aluminum, and iron are formed by metal atoms. The structure of metallic crystals is often described as a uniform distribution of atomic nuclei within a “sea” of delocalized electrons. The atoms within such a metallic solid are held together by a unique force known as metallic bonding that gives rise to many useful and varied bulk properties.
All metallic solids exhibit high thermal and electrical conductivity, metallic luster, and malleability....
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Oxidation Numbers03:14

Oxidation Numbers

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In redox reactions, the transfer of electrons occurs between reacting species. Electron transfer is described by a hypothetical number called the oxidation number (or oxidation state). It represents the effective charge of an atom or element, which is assigned using a set of rules.
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Network Covalent Solids02:18

Network Covalent Solids

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Network covalent solids contain a three-dimensional network of covalently bonded atoms as found in the crystal structures of nonmetals like diamond, graphite, silicon, and some covalent compounds, such as silicon dioxide (sand) and silicon carbide (carborundum, the abrasive on sandpaper). Many minerals have networks of covalent bonds.
To break or to melt a covalent network solid, covalent bonds must be broken. Because covalent bonds are relatively strong, covalent network solids are typically...
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相关实验视频

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Development and Validation of Chromium Getters for Solid Oxide Fuel Cell Power Systems
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Development and Validation of Chromium Getters for Solid Oxide Fuel Cell Power Systems

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一个用于下一代固体氧化物燃料电池的高性能阴极.

Zongping Shao1, Sossina M Haile

  • 1Materials Science, California Institute of Technology, Pasadena, California 91125, USA.

Nature
|September 10, 2004
PubMed
概括

研究人员开发了一种新的正极材料,Ba{0.5}Sr{0.5}Co{0.8}Fe{0.2}O{3-delta) (BSCF),用于固体氧化物燃料电池 (SOFC). 这一进步使得在较低的温度下能够高效运行,解决了SOFC技术的一个关键挑战.

科学领域:

  • 材料科学 材料科学 材料科学
  • 电化学 电化学 电化学
  • 能源转换 能源转换

背景情况:

  • 固体氧化物燃料电池 (SOFC) 提供高效和环保的发电,同时具有燃料灵活性.
  • 传统SOFC的高工作温度 (8001,000°C) 会导致高成本和材料限制.
  • 开发中温 (500700°C) SOFC对于更广泛的采用至关重要,但需要改进的阴极材料.

研究的目的:

  • 引入一种新的正极材料,Ba{0.5}Sr{0.5}Co{0.8}Fe{0.2}O{3-delta) (BSCF),用于降温SOFC操作.
  • 为了评估BSCF在薄膜合化烯酸燃料电池中在中间温度下的性能.
  • 评估BSCF对于单燃料电池配置的适用性.

主要方法:

  • 合成了BSCF,并将其作为阴极材料纳入薄膜化烯燃料电池中.
  • 用加湿作为燃料和空气作为600°C和500°C的阴极气体来测量电化学性能.
  • 研究了通过BSCF材料的氧气扩散率,以了解性能.

主要成果:

  • 基于BSCF的燃料电池在600°C时实现了高功率密度的1,010 mW cm-2和在500°C时达到402 mW cm-2.
  • 该材料在单燃料电池操作中表现出色.

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  • 通过BSCF的高氧气扩散率被确定为其高功率输出的原因.
  • 结论:

    • BSCF是中温SOFC的有前途的阴极材料,克服了传统材料的局限性.
    • 该材料的高性能和适合单操作,为实际的SOFC实施铺平了道路.
    • 通过BSCF实现的降低工作温度可以显著降低SOFC成本并扩大其适用性.