氧化和二氧化碳的交替共聚化
Christopher M Byrne1, Scott D Allen, Emil B Lobkovsky
1Department of Chemistry and Chemical Biology, Baker Laboratory, Cornell University, Ithaca, NY 14853, USA.
Journal of the American Chemical Society
|September 16, 2004
概括
这项研究报告了使用催化剂对氧化和二氧化碳的共聚合. 该工艺产生高纯度,区域常规的聚碳酸盐,具有受控的分子量.
科学领域:
- 聚合物化学 聚合物化学
- 有机金属催化工艺
- 绿色化学 绿色化学
背景情况:
- 氧化是生物基的环氧化物单体.
- 在聚合物合成中利用二氧化碳是一个活跃的研究领域.
- 开发有效的CO2共聚合催化剂至关重要.
研究的目的:
- 报告氧化和二氧化碳的交替共聚变.
- 为了研究β-二胺酸酸催化剂的疗效.
- 为了描述由此产生的聚碳酸的特性.
主要方法:
- 在CO2压力下的交替共聚反应.
- 使用的 (R) 或 (S) 氧化物作为环氧化物单体.
- 采用β-二胺酸酸作为催化剂.
主要成果:
- 对于聚碳酸的转异构体具有很高的选择性.
- 区域常规聚碳酸盐的生产>99%的碳酸盐连接.
- 实现了狭窄的分子量分布.
结论:
- β-二胺酸酸催化剂对于氧化和CO2共聚合是有效的.
- 反应产生高纯度,区域常规的聚碳酸盐.
- 催化剂活性与环氧化物与的比率一致.
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