通过光触发自组装的气结合的粉丝圈
Shiki Yagai1, Toshiharu Nakajima, Takashi Karatsu
1Contribution from the Department of Materials Technology, Faculty of Engineering, and Department of Physics, Faculty of Science, Chiba University, 1-33 Yayoi-cho, Inage-ku, Chiba 263-8522, Japan.
Journal of the American Chemical Society
|September 16, 2004
概括
研究人员使用亚博烯附加的胺 (M2) 和巴比酸盐 (B2) 开发了光响应的超分子组件. 光会触发稳定的循环六合体粉圈的形成,证明了先进材料的可控自组装.
科学领域:
- 超分子化学 超分子化学
- 有机化学 有机化学
- 材料科学 材料科学 材料科学
背景情况:
- 阿佐二衍生物是光敏的分子.
- 具有键的超分子组合具有可调节的特性.
- 胺和巴比酸盐单位可以形成稳定的复合物.
研究的目的:
- 设计和合成光反应超分子组件.
- 研究由亚博烯添加的胺-巴比酸复合物的形成和性质.
- 为了实现超分子结构的光触发形成.
主要方法:
- 合成亚博烯附加的胺 (M2) 和巴比酸盐 (B2) 用三二氧化 (TDP) 形.
- 使用尺寸排除色谱,动态光散射, (1) H NMR 和紫外线光谱学对循环六合体 () 的表征.
- 在紫外线和可见光照射下对阿佐子部分的光异构化研究 (E到Z).
主要成果:
- 在各种溶剂中形成了一个稳定的循环六合体EE-M2(3).B2(3) .
- 对TDP的绝缘挤压抑制了红体内的光异构化.
- 由于硬质障碍,ZZ-M2与B2的复杂性减少.
- 可见光辐射触发了由ZZ-M2和B2混合物形成的花.
结论:
- TDP的固体质量影响了阿佐二烯的光异构化和复杂化.
- 可光调节的复合效率允许光触发的超分子组合.
- 这项工作展示了一种用于光化学控制联花束形成的方法.
相关概念视频
The Photochemical Reaction Center
Reaction centers are pigment-protein complexes that initiate energy conversion from photons to chemical entities. Therefore, photochemical reaction center is a more appropriate term that describes these complexes. The Nobel laureates Robert Emerson and William Arnold provided the first experimental evidence of photochemical reaction centers by demonstrating the participation of nearly 2,500 chlorophyll molecules for the release of just one molecule of oxygen. Despite thousands of photosynthetic...
The Antenna Complex
Plants and other photosynthetic organisms comprise pigments capable of absorption of direct sunlight. These pigments are present in the reaction center - the main site of photochemical reactions as well as in the antenna complex. Under average light conditions, the rate at which reaction center pigments absorb light is far below the electron transport chain's capacity. As a result, the reaction center alone cannot provide enough energy to drive photosynthesis. The photosynthetic efficiency can...
Mechanism of Filopodia Formation
Filopodia are thin, actin-rich cellular protrusions that play an important role in many fundamental cellular functions. They vary in their occurrence, length, and positioning in different cell types, suggesting their diverse roles.
Their main function is to guide migrating cells during normal tissue morphogenesis or cancer metastasis by recognizing and making initial contacts with the extracellular matrix. However, they can also act as stationary cell anchors or help to establish communication...
Their main function is to guide migrating cells during normal tissue morphogenesis or cancer metastasis by recognizing and making initial contacts with the extracellular matrix. However, they can also act as stationary cell anchors or help to establish communication...
Amplifying Signals via Enzymatic Cascade
When a ligand binds to a cell-surface receptor, the receptor's intracellular domain changes shape, which may either activate its enzyme function or allow its binding to other molecules. The initial signal is amplified by most signal transduction pathways. This means that a single ligand molecule can activate multiple molecules of a downstream target. Proteins that relay a signal are most commonly phosphorylated at one or more sites, activating or inactivating the protein. Kinases catalyze the...
Van de Graaff Generator
Van de Graaff generators (or Van de Graaffs) are devices used to demonstrate high voltage due to static electricity that can also be used for research. Robert Van de Graaff first built one in 1931 (based on original suggestions by Lord Kelvin) for use in nuclear physics research.
Van de Graaff uses both smooth and pointed surfaces, conductors, and insulators to generate large static charges and, hence, large voltages. A substantial excess charge can be deposited on the sphere because it moves...
Van de Graaff uses both smooth and pointed surfaces, conductors, and insulators to generate large static charges and, hence, large voltages. A substantial excess charge can be deposited on the sphere because it moves...
Carrier Generation and Recombination
Carrier generation is the process by which electron-hole pairs (EHPs) are created within the semiconductor. In direct-bandgap semiconductors, such as gallium arsenide (GaAs), this occurs efficiently when energy absorption prompts valence electrons to leap into the conduction band, leaving behind holes.
This process is given by the generation rate G and is efficient due to the conservation of momentum between the valence band maximum and conduction band minimum.
Indirect generation involves an...
This process is given by the generation rate G and is efficient due to the conservation of momentum between the valence band maximum and conduction band minimum.
Indirect generation involves an...


