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Determination of the Gas-phase Acidities of Oligopeptides
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在未溶化酸中直接探测zwitterion形成

Rodolphe Antoine1, Michel Broyer, Philippe Dugourd

  • 1Laboratoire de Spectrométrie Ionique et Moléculaire, UMR No. 5579, CNRS et Université Lyon 1, 43 bd du 11 novembre 1918, 69622 Villeurbanne Cedex, France.

Journal of the American Chemical Society
|September 17, 2004
PubMed
概括

基于氨酸的的电感受性揭示了它们的电荷分布. 测量结果与正规形式一致,这表明zwitterions由于分子内约束而在热方面不利.

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