使用氧化还原反应控制粘性弹性
Koji Tsuchiya1, Yoichi Orihara, Yukishige Kondo
1Faculty of Science and Technology, Tokyo University of Science, 2641 Yamazaki, Noda, Chiba 278-8510, Japan.
Journal of the American Chemical Society
|September 30, 2004
概括
研究人员使用可回氧切换的表面活性剂 (11-ferrocenylundecyl) 三甲基化物 (FTMA) 调整了液体的粘性弹性. 电化学氧化破坏了类似虫的微粒,大大降低了粘度和弹性,证明了一种新的电气学效应.
科学领域:
- 材料科学 材料科学 材料科学
- 物理化学 物理化学
- 体科学 体科学 体科学
背景情况:
- 液体粘弹性在各种应用中至关重要.
- 通过电化学控制质性质,提供了新的功能.
- 像 (11-ferrocenylundecyl) 三甲基化物 (FTMA) 这样的表面活性剂可以形成复杂的结构.
研究的目的:
- 为了研究水性FTMA溶液的电学特性.
- 探索FTMA的氧化还原状态在流体粘弹性中的作用.
- 为了展示这种可调节系统的潜在应用.
主要方法:
- 使用 (11-ferrocenylundecyl) 三甲基化物 (FTMA) 作为可回氧切换的表面活性剂.
- 在与盐酸盐 (NaSal) 的水溶液中形成了类似虫的微粒.
- 应用了电化学氧化来改变FTMA状态并观察rheological变化.
主要成果:
- 减少的FTMA形成了纠的虫状,导致显著的粘性弹性.
- FTMA的电解氧化导致了菌体的破坏.
- 在氧化后观察到粘度的显著下降和弹性丧失.
结论:
- FTMA的法拉戴反应使调节的流体具有粘性弹性.
- 电学现象是由可逆形成和虫状细胞的破坏驱动的.
- 潜在的应用包括喷墨印刷,控制释放和流量控制.
相关概念视频
Redox Reactions
Oxidation-reduction or redox reactions involve the transfer of electrons from one molecule or atom to another. When an atom gains an electron, another atom must lose an electron, meaning oxidation and reduction must occur together. Since the redox occurs in pairs, the atom that gets oxidized is also called the reducing agent or reductant, and the atom that is reduced is also called the oxidizing agent or oxidant. A straightforward way to remember the definitions of oxidation and reduction is...
Oxidation-Reduction Reactions
Oxidation–Reduction Reactions
Oxidative Cleavage of Alkenes: Ozonolysis
In ozonolysis, ozone is used to cleave a carbon–carbon double bond to form aldehydes and ketones, or carboxylic acids, depending on the work-up.
Ozone is a symmetrical bent molecule stabilized by a resonance structure.
Ozone is a symmetrical bent molecule stabilized by a resonance structure.
Oxidation and Reduction of Organic Molecules
Energy production within a cell involves many coordinated chemical pathways. Most of these pathways are combinations of oxidation and reduction reactions, which occur at the same time. An oxidation reaction strips an electron from an atom in a compound, and the addition of this electron to another compound is a reduction reaction. Because oxidation and reduction usually occur together, these pairs of reactions are called redox reactions.
The removal of an electron from a molecule, results in a...
The removal of an electron from a molecule, results in a...
Electrophilic Addition of HX to 1,3-Butadiene: Thermodynamic vs Kinetic Control
The addition of a hydrogen halide to 1,3-butadiene gives a mixture of 1,2- and 1,4-adducts. Since more substituted alkenes are more stable, the 1,4-adduct is expected to be the major product. However, the product distribution is strongly influenced by temperature; low temperature favors the 1,2-adduct, whereas the 1,4-adduct is predominant at high temperature.
Bioreactor Controls-II
In aerobic fermentations, oxygen is vital for microbial growth and metabolite production. Since air comprises only about 20% oxygen and the gas is poorly soluble in water—just 9 ppm at 20°C—supplying sufficient oxygen becomes a critical challenge, especially in high-demand processes like yeast growth or citric acid production. Even a fully saturated broth may offer only a few seconds of oxygen availability.To address this, sterile or scrubbed air is introduced into the fermentor via a sparger...


