聚二二三甲-4,5-二-1,3-二氧化物-共四乙烯 (Teflon AF) 的含量有多大?
Hong Zhao1, Kamal Ismail, Stephen G Weber
1Department of Chemistry, University of Pittsburgh, Pittsburgh, Pennsylvania 15260, USA.
Journal of the American Chemical Society
|October 14, 2004
概括
烯酸AF 2400薄膜,当暴露在甲等溶剂,成为塑化,显著增加溶液扩散. 这是一种性聚合物.
科学领域:
- 聚合物科学 聚合物科学
- 材料科学是一种材料科学.
- 化学工程是化学工程的组成部分.
背景情况:
- 烯酸AF 2400是一种稳定,透的聚合物.
- 它作为溶液的运输/提取介质的潜力尚未被探索.
研究的目的:
- 为了研究Teflon AF 2400作为一种新型的运输/提取介质.
- 了解溶剂暴露对其运输特性的影响.
主要方法:
- 研究了各种溶液在甲溶液中的运输行为,通过Teflon AF 2400膜.
- 在聚合物薄膜中测量了的分离和扩散.
- 研究了Krytox FSH在Teflon AF 2400薄膜上的塑化作用.
主要成果:
- 形式在高度 (1.13 M) 中被吸收,使薄膜变质.
- 二醇扩散系数在和平衡膜中增加了3个数量级.
- 极地溶解物3-氧氨酸的分离受到介质的显著影响.
- 克里托克斯FSH塑化了膜,将Tg降低到-40°C,并使分子识别成为可能.
- 与克里托克斯FSH的非对应性关联增加了3-氧氨酸的分布比率41倍.
结论:
- 烯酸AF 2400的运输特性高度依赖于溶剂暴露.
- 溶剂吸附可塑化聚合物,增强溶液扩散.
- 烯酸AF 2400薄膜的性质在有机溶剂浸泡后降低.
相关概念视频
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