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Updated: Jul 14, 2026

Preparation of Highly Porous Coordination Polymer Coatings on Macroporous Polymer Monoliths for Enhanced Enrichment of Phosphopeptides
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通过纳米多孔金属有机框架对的歇斯底里吸附和脱附

Xuebo Zhao1, Bo Xiao, Ashleigh J Fletcher

  • 1Northern Carbon Research Laboratories, School of Natural Sciences, Bedson Building, University of Newcastle upon Tyne, Newcastle upon Tyne, NE1 7RU, UK.

Science (New York, N.Y.)
|October 16, 2004
PubMed
概括

研究人员开发了新的纳米孔金属有机框架,可以动态打开以捕获和存储气. 在储存材料的这一突破提供可逆吸附和脱吸,即使在低压下.

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Metal ions can be separated from one another by complexation with organic ligands–the chelating agent– to form uncharged chelates. Here, the chelating agent must contain hydrophobic groups and behave as a weak acid, losing a proton to bind with the metal. Since most organic ligands used in this process are insoluble or undergo oxidation in the aqueous phase, the chelating agent is initially added to the organic phase and extracted into the aqueous phase. The metal-ligand complex is formed in...