稳定的低压集群存储在一个二元酸盐水合物中
Louw J Florusse1, Cor J Peters, Joop Schoonman
1Faculty of Applied Sciences, Department of Chemical Technology, Physical Chemistry and Molecular Thermodynamics, Delft Institute for Sustainable Energy; Delft University of Technology, Julianalaan 136, 2628 BL Delft, Netherlands.
概括
稳定的储存是通过使用sII二元酸盐水合物实现的. 二联合占用子,大大降低了 (H2) 克拉酸盐形成所需的压力.
科学领域:
- 材料科学 材料科学 材料科学
- 化学工程是化学工程的重要组成部分.
- 物理化学 物理化学
背景情况:
- (H2) 酸盐水合物是气体储存的潜在媒介.
- 形成纯H2酸盐通常需要高压,限制了实际应用.
- 用客分子稳定酸盐结构是一种已知的修改其性质的策略.
研究的目的:
- 用二进制系统研究类酸盐酸盐的稳定.
- 为了确定在降低压力下储存的可行性.
- 描述H2占用酸盐的结构和稳定性.
主要方法:
- 热力学测量热力学测量
- 进行X射线衍射分析.
- 拉曼光谱法 拉曼光谱法
- 核磁共振 (NMR) 光谱学 核磁共振 (NMR) 光谱学
主要成果:
- 聚类的H2分子被成功地稳定在小子的sII酸盐水合物.
- 甲基 (THF) 分子单独占据了大型子,作为稳定共同客人.
- 二元酸盐系统允许在明显较低的压力下储存H2 (5MPa在279.6K) 与纯酸盐 (300MPa在280K) 相比.
结论:
- 二元酸盐水合物为低压储存提供了一个有前途的途径.
- 子由H2和THF共同占用,有效地稳定了酸盐结构.
- 这一发现对开发高效和安全的储存技术有影响.
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