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在三氨基酸中进行了一种新的重新排列过程

Valerije Vrcek1, Martin Saunders, Olga Kronja

  • 1Contribution from the Faculty of Pharmacy and Biochemistry, University of Zagreb, A. Kovacića 1, 10000 Zagreb, Croatia.

Journal of the American Chemical Society
|October 21, 2004
PubMed
概括

碳-13核磁共振光谱揭示了19.5 kcal/mol的碳交换在三氨基离子中的障碍. 这种重新排列涉及化物转移和质子化环烯中间体,在内外碳交换中发现的最高能量屏障.

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