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铁的制备和分子和电子结构 (((0) 二和西兰复合物及其在催化化和水化中的应用
Suzanne C Bart1, Emil Lobkovsky, Paul J Chirik
1Department of Chemistry and Chemical Biology, Baker Laboratory, Cornell University, Ithaca, New York 14853, USA.
Journal of the American Chemical Society
|October 21, 2004
概括
新的铁(0) 二复合物, (iPrPDI) Fe(N2) 2 和 (iPrPDI) Fe(N2),是烯和烯化和化有效的前催化剂. 这些催化剂在低负载和环境温度下有效运行,在水化反应中提供选择性的反马尔科夫尼科夫产物形成.
科学领域:
- 有机金属化学 有机金属化学
- 催化剂是一种催化剂.
背景情况:
- 铁复合物在催化过程中至关重要.
- 二联体可以稳定低价值金属中心.
研究的目的:
- 为了合成和表征新的铁(0) 二复合物.
- 评估它们在化和水化反应中的前催化剂的有效性.
主要方法:
- 在二气氛下用合金减少铁 (II) 前体.
- 由此产生的铁(0) 复合物的光谱和结构特征.
- 对不和基质的化和水化进行催化试验.
主要成果:
- 合成正方形的金字塔形,高旋转铁 ((0) bis (((二) 复合物 (iPrPDI) Fe (((N2) 2) 和其单一 (((二)) 添加物 (iPrPDI) Fe (((N2) 2).
- 这两种复合物都在低负载 (<0.3 mol%) 时表现出高效的预催化活性,用于化和化烯和烯的化.
- 催化水选择性地产生了抗马尔科夫尼科夫产物;从中间体和同位素标签的结构研究中获得了机械洞察力.
结论:
- 新型铁(0) 二复合物是化和水化的强有力的前催化剂.
- 催化系统提供高效率,选择性和机械处理性.
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