铁的制备和分子和电子结构 (((0) 二和西兰复合物及其在催化化和水化中的应用

Suzanne C Bart1, Emil Lobkovsky, Paul J Chirik

  • 1Department of Chemistry and Chemical Biology, Baker Laboratory, Cornell University, Ithaca, New York 14853, USA.

概括

新的铁(0) 二复合物, (iPrPDI) Fe(N2) 2 和 (iPrPDI) Fe(N2),是烯和烯化和化有效的前催化剂. 这些催化剂在低负载和环境温度下有效运行,在水化反应中提供选择性的反马尔科夫尼科夫产物形成.

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