一种光结合聚电解质的发光灭
Ksenija Haskins-Glusac1, Mauricio R Pinto, Chunyan Tan
1Department of Chemistry, University of Florida, Gainesville, FL 32611-7200, USA.
Journal of the American Chemical Society
|November 13, 2004
概括
这项研究报告了基于的合聚电解质,Pt-p及其光灭特性. 与光聚合物不同,Pt-pp是一种光聚合物.
科学领域:
- 材料科学 材料科学 材料科学
- 聚合物化学 聚合物化学
- 光物理学的光学物理学
背景情况:
- 结合的多电解质因其独特的光物理性质而受到研究.
- (II) 乙化物聚合物为新型发光应用提供了潜力.
研究的目的:
- 为了研究白金(II) 乙化物基结合聚合电解质 (Pt-p) 的光物理和发光灭特性.
- 为了比较Pt-p的灭行为与光有机聚电解质.
主要方法:
- (II) 乙基结合多电解质 (Pt-p) 的合成和表征.
- 对光特性的研究.
- 使用带有不同电荷 (MV(+),MV(2+),MV(4+)) 的紫光剂进行发光灭研究.
- 斯特恩-沃尔默分析以确定火机制.
主要成果:
- 溶于水的 Pt-p 呈现出源于对联脊柱上的三重 pi,pi 激子的光.
- 光灭由viologens遵循一个动态 (扩散) 机制.
- 光合聚电解质的典型放大火效应,对于Pt-p来说并不显著.
结论:
- 与光对应物相比,乙酸光联聚电解质显示出不同的灭行为.
- 动态火机制是Pt-p的主导作用.
- 放大火效应并不是所有合聚电解质的普遍特征.
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