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控制Bergman循环的基态和兴奋状态热障碍,使用基结末替代

Mahendra Nath1, Maren Pink, Jeffrey M Zaleski

  • 1Department of Chemistry, Indiana University, Bloomington, Indiana 47405, USA.

Journal of the American Chemical Society
|January 13, 2005
PubMed
概括

这项研究合成了新的dialkynylporphyrins及其复合物,通过热和光解途径调查了它们的伯格曼循环. 反应性受到侧链的影响,未被替代的类似物在循环反应中表现出更高的产量.

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