对于高电光活性材料的新方法,使用可交叉链接的,超分支的染色体含有寡合体作为宏分子剂
Yaowen Bai1, Naiheng Song, Jian Ping Gao
1Department of Chemistry, Carleton University, 1125 Colonel By Drive, Ottawa, Ontario, K1S 5B6, Canada.
Journal of the American Chemical Society
|February 17, 2005
概括
研究人员开发了一种新的聚合物混合物,用于使用超分支的寡合物多剂的电光设备. 这种方法为非线性光学 (NLO) 应用提供了更好的性能和稳定性.
科学领域:
- 聚合物科学 聚合物科学
- 材料科学 材料科学 材料科学
- 光电学是指光电子产品.
背景情况:
- 开发电光活性聚合物对于先进的光学设备至关重要.
- 现有的材料,如线性聚合物和客宿主系统在性能和稳定性方面存在局限性.
研究的目的:
- 介绍一种新的实用方法,用于创建高电光活性聚合物材料.
- 使用具有非线性光学 (NLO) 染色体的热交叉链接,超分支的寡合体作为宏分子剂.
主要方法:
- 在宿主聚合物中使用超分支的寡合物剂制备非线性光学 (NLO) 聚合物混合物.
- 描述配方混合物的电光学 (EO) 特性,包括系数和时间稳定性.
主要成果:
- 成功配制的NLO聚合物混合物具有大而稳定的电光 (EO) 系数,高达65pm/V.
- 与传统的NLO聚合物和客宿主系统相比,证明了更好的抛光效率和时间稳定性.
结论:
- 使用超分支寡合物作为剂的新方法为电光器件开发提供了显著的优势.
- 这种方法可以实现多功能材料配方,提高NLO应用的性能.
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