富勒的转变 富勒的转变
R James Cross1, Martin Saunders
1Department of Chemistry, Yale University, PO Box 208107, New Haven, Connecticut 06520-8107, USA. james.cross@yale.edu
Journal of the American Chemical Society
|March 3, 2005
概括
像C76,C78和C84这样的较大的富勒烯的热解导致碳损失和较小的富勒烯形成. 在C76中封装的大部分丢失,而C60在高温分解过程中保持完整.
科学领域:
- 富勒的化学结构
- 高温材料科学 高温材料科学
背景情况:
- 富勒烯是碳的异构体,具有独特的形结构.
- 了解热应力下的富勒烯稳定性对于它们的应用至关重要.
研究的目的:
- 研究各种富勒烯的热分解路径.
- 为了确定热解对富勒烯结构和封装物种的影响.
主要方法:
- 富勒的升华成气.
- 在约1000°C的烤箱中进行热解.
- 对分解产品和封装保留的分析.
主要成果:
- C76,C78和C84很容易失去碳原子,形成较小的富勒烯.
- 在热解过程中观察到C78的异构.
- (3) He@C76的热解导致封装的大量损失.
- C60表现出高热稳定性,没有分解或损失.
结论:
- 较大的富勒烯在高温下容易经历碳挤出和碎片化.
- 封装物种的稳定性随着富勒伦子的大小而有很大变化.
- C60具有显著的热弹性,使其适合在高温环境中使用.
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