对于区域常规的多3-基烯薄膜的粘弹性特性,时间-温度叠加
A Robert Hillman1, Igor Efimov, Magdalena Skompska
1Department of Chemistry, University of Leicester, Leicester LE1 7RH, UK. arh7@le.ac.uk
Journal of the American Chemical Society
|March 18, 2005
概括
聚3-基thiophene) 薄膜中的剪切模块根据聚合方法不同. 侧链动态,而不是脊柱运动,控制放松,由时间温度叠加揭示.
科学领域:
- 材料科学 材料科学 材料科学
- 聚合物物理 聚合物物理
- 有机电子 有机电子
背景情况:
- 聚3-甲) (P3HT) 是一个关键的有机半导体.
- 了解其机械性能对于设备应用至关重要.
- 之前对P3HT机械性能的研究主要集中在电聚合膜上.
研究的目的:
- 为了确定化学聚合和溶剂造区域常规P3HT薄膜的剪切模块.
- 为了研究测量时间尺度和温度对薄膜力学的影响.
- 为了比较机械行为与电聚合区域随机P3HT.
主要方法:
- 厚度剪切模式声波共振器被用于测量剪切模块.
- 测量时间尺度是使用更高的波和温度变化的.
- 时间-温度叠加被应用来使应力放松数据正常化.
主要成果:
- 化学聚合/溶剂造区域常规P3HT膜的剪切模块与电聚合区域随机膜相比表现出不同的行为.
- 切削模量与时间尺度的显著变化被正常化到主放松曲线上.
- 正常化的转移因子遵循阿雷尼乌斯式行为,而不是WLF,表明侧链动态.
结论:
- 在P3HT薄膜中的机械放松是由六侧链动力学主导的,而不是聚合物骨干运动.
- 对于电活性薄膜,时间-温度叠加被成功证明.
- 观察到的行为与区别的阶段和分子包装在regioregular与regiorandom P3HT.相一致.
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