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Updated: Jul 10, 2026

Accessing Valuable Ligand Supports for Transition Metals: A Modified, Intermediate Scale Preparation of 1,2,3,4,5-Pentamethylcyclopentadiene
09:45

Accessing Valuable Ligand Supports for Transition Metals: A Modified, Intermediate Scale Preparation of 1,2,3,4,5-Pentamethylcyclopentadiene

Published on: March 20, 2017

过渡金属催化分子间 [5+2] 和 [5+2+1] 循环添加剂的艾伦和乙烯基cyclopropanes

Hermann A Wegner1, Armin de Meijere, Paul A Wender

  • 1Departments of Chemistry and Molecular Pharmacology, Stanford University, Stanford, CA 94305, USA.

Journal of the American Chemical Society
|May 5, 2005
PubMed
概括

研究人员报告了新的Rh(I) 催化 [5+2] 循环添加反应,使用双功能阿伦和乙烯基cyclopropanes. 这种方法有效地合成了循环载荷管道,并通过三组件的 [5+2+1] 循环添加,与一氧化碳形成八个成员的环.

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