碳纳米管和纳米带的可控制造,采用聚氧甲酸盐辅助的温和热水工艺
Zhenhui Kang1, Enbo Wang, Baodong Mao
1Institute of Polyoxometalate Chemistry, Department of Chemistry, Northeast Normal University, Changchun, Jilin 130 024, P. R. China.
Journal of the American Chemical Society
|May 5, 2005
概括
活性碳粉末可以通过通过聚氧甲酸盐 (POMs) 辅助的温和水热过程转化为碳纳米管,纳米带和纳米颗粒. 在反应后,POMs被再生,使其能够进一步使用.
科学领域:
- 材料科学 材料科学 材料科学
- 纳米技术 纳米技术
- 化学 化学 化学
背景情况:
- 活性碳材料是多用途的前体.
- 碳纳米结构的受控合成对于先进的应用至关重要.
- 聚氧甲酸盐 (POM) 具有独特的催化和结构性质.
研究的目的:
- 开发一种温和的热水方法来合成碳纳米结构.
- 为了利用活性碳粉作为直接前体.
- 研究聚氧甲酸盐 (POMs) 在合成过程中的作用.
主要方法:
- 采用了温和的热水过程.
- 活性碳粉末被用作起始材料.
- 聚氧甲酸盐 (POMs) 在反应中起到辅助作用.
主要成果:
- 碳纳米管,碳纳米带和碳纳米粒子已经成功地准备好了.
- 该过程直接将活性碳粉转化为各种纳米结构.
- 观察到多氧甲酸盐 (POMs) 在反应后转化为异构蓝色.
- 使用过氧化 (H2O2) 实现了POMs的再生.
结论:
- 从活性碳中合成各种碳纳米结构的简单有效方法被确立.
- POM辅助的热水过程为纳米碳生产提供了一个有前途的途径.
- 证明了POMs的可回收性,这表明了可持续合成的潜力.
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