两个化学上不同的有机池积聚在海洋中
Lihini I Aluwihare1, Daniel J Repeta, Silvio Pantoja
1Geosciences Research Division, Scripps Institution of Oceanography, La Jolla, CA 92093, USA. laluwihare@ucsd.edu
概括
海洋溶解有机 (DON) 档案是由两个不同的胺池形成的. 地表水中含有N-乙氨基多糖,而深海DON由耐性胺基组成,影响循环.
科学领域:
- 海洋化学 海洋化学
- 生物地质化学循环 生物地质化学循环
- 有机地化学 有机地化学
背景情况:
- 海洋溶解有机 (DON) 在表面积累,即使在有限的地区.
- 海洋DON的化学性质和动态仍然不太清楚.
- 了解DON对于海洋生产力和循环至关重要.
研究的目的:
- 为了研究高分子量DON (HMW-DON) 的化学成分.
- 确定导致海洋垂直DON形状的因素.
- 在HMW-DON中区分各种胺键类型.
主要方法:
- 利用HMW-DON中胺键的酸可变性差异.
- 化学水解的实验.
- 在表面和深海水样本中分析HMW-DON成分.
主要成果:
- 在HMW-DON中确定了两个化学上不同的胺池.
- 表面HMW-DON由大约50%的N-乙氨基多糖组成.
- 深海HMW-DON主要由抗化学和生物降解的胺基组成.
结论:
- 垂直的DON形状部分是由这两个不同的胺池的存在解释的.
- 深海HMW-DON胺的反抗性质表明它们的停留时间很长.
- 这些发现增强了我们对海洋循环和DON作用的理解.
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