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Crystal Field Theory - Octahedral Complexes02:58

Crystal Field Theory - Octahedral Complexes

Crystal Field Theory
To explain the observed behavior of transition metal complexes (such as colors), a model involving electrostatic interactions between the electrons from the ligands and the electrons in the unhybridized d orbitals of the central metal atom has been developed. This electrostatic model is crystal field theory (CFT). It helps to understand, interpret, and predict the colors, magnetic behavior, and some structures of coordination compounds of transition metals.
CFT focuses on...
Regioselectivity and Stereochemistry of Acid-Catalyzed Hydration02:34

Regioselectivity and Stereochemistry of Acid-Catalyzed Hydration

The rate of acid-catalyzed hydration of alkenes depends on the alkene's structure, as the presence of alkyl substituents at the double bond can significantly influence the rate.
Reduction of Alkynes to cis-Alkenes: Catalytic Hydrogenation02:24

Reduction of Alkynes to cis-Alkenes: Catalytic Hydrogenation

Introduction
Like alkenes, alkynes can be reduced to alkanes in the presence of transition metal catalysts such as Pt, Pd, or Ni. The reaction involves two sequential syn additions of hydrogen via a cis-alkene intermediate.
α-Alkylation of Ketones via Enolate Ions01:10

α-Alkylation of Ketones via Enolate Ions

Ketones with α protons are deprotonated by strong bases like lithium diisopropylamide (LDA) to form enolate ions. The anion is stabilized by resonance, and its hybrid structure exhibits negative charges on the carbonyl oxygen and the α carbon. This ambident nucleophile can attack an electrophile via two possible sites: the carbonyl oxygen, known as O-attack, or the α carbon, known as C-attack. The nucleophilic attack via the carbanionic site is preferred. This is due to the strong interaction...
[3,3] Sigmatropic Rearrangement of 1,5-Dienes: Cope Rearrangement01:21

[3,3] Sigmatropic Rearrangement of 1,5-Dienes: Cope Rearrangement

The Cope rearrangement is classified as a [3,3] sigmatropic shift in 1,5-dienes, leading to a more stable, isomeric 1,5-diene. The reaction involves a concerted movement of six electrons, four from two π bonds and two from a σ bond, via an energetically favorable chair-like transition state.
[3,3] Sigmatropic Rearrangement of Allyl Vinyl Ethers: Claisen Rearrangement01:24

[3,3] Sigmatropic Rearrangement of Allyl Vinyl Ethers: Claisen Rearrangement

The Claisen rearrangement is a [3,3] sigmatropic rearrangement of allyl vinyl ethers to unsaturated carbonyl compounds. The rearrangement is a concerted pericyclic reaction proceeding via a chair-like transition state.

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相关实验视频

Updated: Jul 14, 2026

Accessing Valuable Ligand Supports for Transition Metals: A Modified, Intermediate Scale Preparation of 1,2,3,4,5-Pentamethylcyclopentadiene
09:45

Accessing Valuable Ligand Supports for Transition Metals: A Modified, Intermediate Scale Preparation of 1,2,3,4,5-Pentamethylcyclopentadiene

Published on: March 20, 2017

在 (Arene) Cr ((CO) 2L系列中加速的烯配体交换.

M F Semmelhack1, Anatoly Chlenov, Douglas M Ho

  • 1Department of Chemistry, Princeton University, Princeton, New Jersey 08544, USA. mfshack@princeton.edu

Journal of the American Chemical Society
|May 26, 2005
PubMed
概括

新的素配体加速了 () Cr (Cr) CO (CO) 2L复合体中的烯配体交换. 电子不对称的双酸配体,特别是那些含有-CO2Me,-CONMe2和2-pyridinyl替代剂的配体,显著增加了汇率.

科学领域:

  • 有机金属化学 有机金属化学
  • 协调化学 协调化学
  • 催化剂是一种催化剂.

背景情况:

  • 配体交换反应是有机金属化学的基础,影响反应性和催化循环.
  • 众所周知, (arene) Cr ((CO) 2L 复合序列具有 arene 连接体交换,但速度可以由连接体 L. 调节.
  • 电子不对称的双酸连接物已经显示出加速这些交换过程的潜力.

研究的目的:

  • 为了合成和评估新型的tris(pyrrolyl) 素衍生物作为 (arene) Cr ((CO) 2L复合体中的配体 (L).
  • 为了研究各种2-L'-替代剂对醇环对烯联结物交换速率的影响.
  • 探索这些替代剂影响激活能量用于交换的机制.

主要方法:

  • 合成一系列具有多种功能组的2-L'-替代型醇 (例如,-SMe, -CO2Me, -2-pyridinyl).
  • 通过与ClP (pyrrolyl) 的反应制备新的素连接体, (2-L'-pyrrolyl) ((pyrrolyl) 2P) 2.
  • 形成相应的 (arene) Cr ((CO) 2[P ((2-L'-pyrrolyl) ((pyrrolyl) 2P]复合体,并使用各种替代的来测量的汇率.

主要成果:

  • 成功合成了一系列新的素连接体及其复合体.

更多相关视频

Facile Preparation of (2Z,4E)-Dienamides by the Olefination of Electron-deficient Alkenes with Allyl Acetate
06:46

Facile Preparation of (2Z,4E)-Dienamides by the Olefination of Electron-deficient Alkenes with Allyl Acetate

Published on: June 21, 2017

Line Shape Analysis of Dynamic NMR Spectra for Characterizing Coordination Sphere Rearrangements at a Chiral Rhenium Polyhydride Complex
10:52

Line Shape Analysis of Dynamic NMR Spectra for Characterizing Coordination Sphere Rearrangements at a Chiral Rhenium Polyhydride Complex

Published on: July 27, 2022

相关实验视频

Last Updated: Jul 14, 2026

Accessing Valuable Ligand Supports for Transition Metals: A Modified, Intermediate Scale Preparation of 1,2,3,4,5-Pentamethylcyclopentadiene
09:45

Accessing Valuable Ligand Supports for Transition Metals: A Modified, Intermediate Scale Preparation of 1,2,3,4,5-Pentamethylcyclopentadiene

Published on: March 20, 2017

Facile Preparation of (2Z,4E)-Dienamides by the Olefination of Electron-deficient Alkenes with Allyl Acetate
06:46

Facile Preparation of (2Z,4E)-Dienamides by the Olefination of Electron-deficient Alkenes with Allyl Acetate

Published on: June 21, 2017

Line Shape Analysis of Dynamic NMR Spectra for Characterizing Coordination Sphere Rearrangements at a Chiral Rhenium Polyhydride Complex
10:52

Line Shape Analysis of Dynamic NMR Spectra for Characterizing Coordination Sphere Rearrangements at a Chiral Rhenium Polyhydride Complex

Published on: July 27, 2022

  • 大多数合成的复合物与具有更简单连接体的类似复合物相比,表现出明显增加的基交换率.
  • 含有 -CO2Me, -CONMe2和 -2-pyridinyl 替代剂的复合物所观察到的加速最为明显,其半衰期在22°C下低至8小时.
  • 结论:

    • 电子不对称的双酸联体,特别是那些具有特定侧链替代剂的联体,有效地加速 (arene) Cr ((CO) 2L复合体中的联体交换.
    • 观察到的速率增强表明,L'替代剂可能会为中心提供临时协调,降低解离的激活屏障.
    • 这些发现为设计更具反应性的有机金属复合物提供了一条途径,用于催化中的潜在应用.