在CH4-xFx中用单体[1,2,4-(Me3C) 3C5H2]2CeH交换的:实验和计算研究

Evan L Werkema1, Elsa Messines, Lionel Perrin

  • 1Chemistry Department and Chemical Sciences Division of Lawrence Berkeley National Laboratory, University of California, Berkeley, California 94720, USA.

概括

单体化经历了与碳化合物的H换F交换反应,形成化. DFT计算显示,随着化增加,CH激活障碍物减少,影响反应速率.

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