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在高T (c) 超导体的粒度边界进行增强的电流传输
R F Klie1, J P Buban, M Varela
1Center for Functional Nanomaterials, Brookhaven National Laboratory, Upton, New York 11973, USA. klie@bnl.gov
将杂质添加到YBCO超导体中,通过改变谷物边界结构来提高电流密度. 这项研究表明,离子大小,而不仅仅是电子电荷,是提高多晶高温超导体性能的关键.
科学领域:
- 材料科学 材料科学 材料科学
- 凝聚物质物理学 凝聚物质物理学
- 超导电性 超导电性 超导电性
背景情况:
- 多晶高过渡温度 (高Tc) 超导体比单晶具有较低的临界电流密度 (Jc),限制了大规模的应用.
- 谷物边界误导角度显著降低了J(c),虽然谷物纹理有所帮助,但问题仍然存在.
- (Ca) 化剂在亚,,铜氧化物 (YBCO) 中增加了J(c),通常归因于Ca2+替代Y3+的过多孔.
研究的目的:
- 阐明在多晶YBCO中增强J (c) 的粒度边界和Ca化作用背后的物理机制.
- 为了研究碳酸杂质和在谷物边界的氧气空缺的原子尺度行为.
主要方法:
- 使用了原子尺度的计算,成像和光谱学.
- 分析的重点是YBCO谷物边界和Ca替代的影响.
主要成果:
- 在多晶YBCO中,高强度的谷物边界区域含有过多的氧气空缺,减少了局部孔度.
- 杂物可以替代Y,但也可以替代Ba和Cu在紧张的谷粒边界区域,减轻压力.
- 这种替代抑制了氧气空缺的形成,从而增强了J.
结论:
- 在Ca-化YBCO中J (c) 的增强主要由剂的离子半径控制,这影响了在粒边界的应变和氧空隙形成.
- 离子尺寸效应比电子价值效应更为关键,以改善这些材料中的J (c).
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