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Updated: Aug 16, 2026

Metal-free Synthesis of Ynones from Acyl Chlorides and Potassium Alkynyltrifluoroborate Salts
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Published on: February 24, 2015

不对称的[2,3]-sigmatropic重新排列的氨基化物

Jan Blid1, Olaf Panknin, Peter Somfai

  • 1Organic Chemistry, KTH Chemistry, Royal Institute of Technology, SE-100 44 Stockholm, Sweden.

Journal of the American Chemical Society
|June 30, 2005
PubMed
概括

一种新的不对称的易斯酸方法可以通过[2,3]-sigmatropic重新排列,从氨酸中合成同样性氨基的enantioselective合成. 这种方法提供了一个强大的工具,可以有效地创建性氨基化合物.

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