在合聚合物中,三重和单重激子的孔诱导火
Andre J Gesquiere1, So-Jung Park, Paul F Barbara
1Center for Nano- and Molecular Science and Technology, Department of Chemistry and Biochemistry, University of Texas at Austin, Austin, Texas 78712, USA.
Journal of the American Chemical Society
|June 30, 2005
概括
新的光谱学揭示了结合聚合物的三重激子被洞有效地灭,与单重激子不同. 这种差异是由于三重刺激子.
科学领域:
- 有机电子学有机电子学
- 结合聚合物的光物理学
- 刺激的动力学 刺激的动力学
背景情况:
- 结合聚合物是有机电子设备的关键材料.
- 了解刺激火机制对于设备的效率至关重要.
- 孔诱导的火会影响电荷生成和重组过程.
研究的目的:
- 量化研究合聚合物中单元和三元激子的孔诱导火.
- 确定通过孔调节激电火的机制和速率.
- 为了比较三重和单重刺激子的火效率.
主要方法:
- 光电压时间解析单分子光谱 (FV-TR-SMS) 的开发和应用.
- 在单个聚合物分子上同时测量光强度,设备偏差和辐射强度.
- 基于测量寿命和密度的刺激火的动力分析.
主要成果:
- 三重激子在密度> 10 16 电荷/厘米的孔中被有效灭.
- 与三重刺激子相比,单重刺激子的火效率明显较低.
- 单片通过孔火的速率常数超过三重火的速率常数数量级,尽管单片寿命较短.
结论:
- 三重激子的寿命较长主导着它们通过孔的高效火.
- 单点激发火效率较低,因为它们的寿命要短得多.
- 在FV-TR-SMS提供了关键的洞察力,对共聚合物的激子动态.
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