奇中的高压结构与磁性有关
S Heathman1, R G Haire, T Le Bihan
1European Commission, Joint Research Centre, Institute for Transuranium Elements, Postfach 2340, D-76125, Karlsruhe, Germany. heathman@itu.fzk.de
概括
在高压下表现出独特的单临晶体结构 (Cm III),其5f电子的自旋极化使其稳定. 这一发现凸显了奇作为一种罕见的元素,其磁性影响其晶格结构.
科学领域:
- 固态物理 固态物理
- 材料科学是一种材料科学.
- 量子化学是一种量子化学.
背景情况:
- 是具有独特电子配置的中心动因化物.
- 在压力下,动氨基酸表现出复杂的晶体相转换.
- 之前对美洲的研究表明,它在结构行为上有相似之处.
研究的目的:
- 为了描述在高压下奇中新的晶体结构.
- 为了研究影响curium结构的电子和磁性特性.
- 了解5f电子自旋偏振在稳定晶相中的作用.
主要方法:
- 高压实验可以达到100千兆帕斯卡尔.
- 通过X射线衍射来识别晶体相.
- 最初的电子结构计算.
主要成果:
- 在37-56千兆帕斯卡尔之间的奇中发现了一种新的单临床结构 (Cm III,空间组C2 / c).
- 这种结构与在美洲中观察到的相不同.
- 电子结构计算证实了观察到的结构序列,并确定了5f电子的自旋极化作为Cm III的稳定因子.
结论:
- 具有独特的高压相 (Cm III),由电子磁力稳定.
- 5f电子的自旋极化在奇的结构行为中起着至关重要的作用.
- 被确定为数不多的元素之一,其中磁性决定了晶格结构.
更多相关视频
09:41Magnet Assisted Composite Manufacturing: A Flexible New Technique for Achieving High Consolidation Pressure in Vacuum Bag/Lay-Up Processes
Published on: May 17, 2018
08:55High-Temperature and High-Pressure In situ Magic Angle Spinning Nuclear Magnetic Resonance Spectroscopy
Published on: October 9, 2020
相关概念视频
Magnetism
Magnets are commonly found in everyday objects, such as toys, hangers, elevators, doorbells, and computer devices. Experimentation on these magnets shows that all magnets have two poles: one is labeled north (N) and the other south (S). Magnetic poles repel if they are alike and attract if unlike. Moreover, both poles of a magnet attract unmagnetized pieces of iron.
An individual magnetic pole cannot be isolated. No matter how small, every piece of a magnet contains a north pole and a south...
An individual magnetic pole cannot be isolated. No matter how small, every piece of a magnet contains a north pole and a south...
Magnetic Fields
A moving charge or a current creates a magnetic field in the surrounding space, in addition to its electric field. The magnetic field exerts a force on any other moving charge or current that is present in the field. Like an electric field, the magnetic field is also a vector field. At any position, the direction of the magnetic field is defined as the direction in which the north pole of a compass needle points.
A magnetic field is defined by the force that a charged particle experiences...
A magnetic field is defined by the force that a charged particle experiences...
Magnetic Force Between Two Parallel Currents
Two long, straight, and parallel current-carrying conductors exert a force of equal magnitude on one another. The direction of the force depends on the current direction in the conductors.
The force exerted by the magnetic field due to the first conductor over a finite length of the second conductor is given as the product of the current in the second conductor and the vector product of the length vector along the current element and the field due to the first conductor. According to the...
The force exerted by the magnetic field due to the first conductor over a finite length of the second conductor is given as the product of the current in the second conductor and the vector product of the length vector along the current element and the field due to the first conductor. According to the...
Magnetic Force
In addition to the electric forces between electric charges, moving electric charges exert magnetic forces on each other. A magnetic field is created by a moving charge or a group of moving charges known as the electric current. A magnetic force is experienced by a second current or moving charge in response to this magnetic field. Fundamentally, interactions between moving electrons in the atoms of two bodies produce magnetic forces between them.
The magnetic force acting on a moving charge...
The magnetic force acting on a moving charge...
Magnetostatic Boundary Conditions
An electric field suffers a discontinuity at a surface charge. Similarly, a magnetic field is discontinuous at a surface current. The perpendicular component of a magnetic field is continuous across the interface of two magnetic mediums. In contrast, its parallel component, perpendicular to the current, is discontinuous by the amount equal to the product of the vacuum permeability and the surface current. Like the scalar potential in electrostatics, the vector potential is also continuous...
Magnetic Susceptibility and Permeability
In linear magnetic materials, like paramagnets and diamagnets, magnetization is proportional to the magnetic field intensity. The constant of proportionality, a dimensionless number, is called magnetic susceptibility. The value of the susceptibility depends on the type of material.
When diamagnetic materials are placed under an external magnetic field, the moments opposite to the field are induced. Hence, the susceptibility for diamagnets has a minimal negative value of 10-5–10-6. Since...
When diamagnetic materials are placed under an external magnetic field, the moments opposite to the field are induced. Hence, the susceptibility for diamagnets has a minimal negative value of 10-5–10-6. Since...
