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Published on: March 20, 2014

关于P-arylphosphiranes的热碎片化的计算研究:这种方法是否产生了arylphosphinidenes?

Wai Han Lam1, Peter P Gaspar, David A Hrovat

  • 1Departments of Chemistry, University of Washington, Box 351700, Seattle, Washington 98195-1700, USA.

Journal of the American Chemical Society
|July 7, 2005
PubMed
概括

计算化学揭示了三重聚烯 (PhP) 通过一个阶段性途径产生,这种途径不那么内热,并且具有较低的激活屏障,而不是对单片 PhP 的协同碎片化.

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