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高度控制的乙在金属有机微孔材料中的安置

Ryotaro Matsuda1, Ryo Kitaura, Susumu Kitagawa

  • 1Department of Synthetic Chemistry and Biological Chemistry, Graduate School of Engineering, Kyoto University, Katsura, Kyoto 615-8510, Japan.

Nature
|July 15, 2005
PubMed
概括

金属有机微孔材料 (MOMs) 显示出对二氧化碳的选择性乙吸附. 这种功能化的MOM可以在200倍的安全压缩极限下稳定储存乙.

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Extraction: Advanced Methods00:56

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Metal ions can be separated from one another by complexation with organic ligands–the chelating agent– to form uncharged chelates. Here, the chelating agent must contain hydrophobic groups and behave as a weak acid, losing a proton to bind with the metal. Since most organic ligands used in this process are insoluble or undergo oxidation in the aqueous phase, the chelating agent is initially added to the organic phase and extracted into the aqueous phase. The metal-ligand complex is formed in...