聚合物玻璃在表面,接口和中间的结构松
Rodney D Priestley1, Christopher J Ellison, Linda J Broadbelt
1Department of Chemical and Biological Engineering, Northwestern University, Evanston, IL 60208, USA.
概括
聚合物结构放松在接近表面和接口时显著减缓. 这种效应延伸到100nm以上的聚合物薄膜中,影响材料性能.
科学领域:
- 聚合物科学 聚合物科学
- 材料科学 材料科学 材料科学
- 物理化学 物理化学
背景情况:
- 了解在接口附近的聚合物动态对于材料设计至关重要.
- 玻璃状结构放松控制着长期的聚合物性能.
- 表面和接口效应可以改变散装聚合物的特性.
研究的目的:
- 量化表面和接口对聚合物结构松的影响.
- 为了确定这些效应在聚合物薄膜中的空间范围.
主要方法:
- 在多层聚合物薄膜中利用光监测.
- 分析了聚甲基酸 (PMMA) 的结构松率.
- 在自由表面和界面与散装PMMA的放松率进行比较.
主要成果:
- 结构放松率在自由表面降低2倍,在接口降低15倍.
- 在二氧化接口上观察到几乎完全停止放松.
- 在聚合物薄膜中观察到高达100nm的放松放缓.
结论:
- 表面和接口大大减缓了聚合物结构放松.
- 这些影响比玻璃过渡温度的变化更深入聚合物.
- 聚合物动态的界面诱导的变化是显著的和远程的.
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