光响应性键花束的层次组织
Shiki Yagai1, Toshiharu Nakajima, Keiki Kishikawa
1Department of Applied Chemistry and Biotechnology, Faculty of Engineering, Chiba University, 1-33 Yayoi-cho, Inage-ku, Chiba 263-8522, Japan. yagai@faculty.chiba-u.jp
Journal of the American Chemical Society
|August 4, 2005
概括
研究人员使用圆盘形的超分子制造了一种新型的光响应器官凝. 这个凝是凝.
科学领域:
- 超分子化学 超分子化学
- 材料科学 材料科学 材料科学
- 有机化学 有机化学
背景情况:
- 与结合的圆盘状聚合物 (粉囊) 是由由亚博添加的胺和巴比酸盐/酸盐组成的.
- 这些罗塞特表现出层次组织和光响应性行为.
研究的目的:
- 调查基于亚博的粉圈的等级组织和光响应行为.
- 使用圆盘形的超分子开发光响应器官凝.
主要方法:
- 核磁共振 (NMR) 光谱学是指核磁共振的光谱学.
- 紫外线/紫外线光谱学
- 动态光散射 (DLS) 是一种
- 凝研究的研究.
- 分子建模分子建模
主要成果:
- 基于巴比酸盐的罗塞特在散装中形成矩形柱状半相,但在溶剂中不是更高阶聚合物.
- 基于酸盐的粉圈在散装和溶剂中的纤维聚合物中形成六角柱状半相,导致有机凝的形成.
- 通过紫外线辐射诱导柱状聚合物的可逆解离和重构,通过亚博二烯跨异构化.
- 分子建模显示,cis-azobenzene红会失去平面性.
结论:
- 基于阿佐的粉圈可以形成柱状中相和器官凝.
- 亚博烯分子使得光控制的自组装和拆卸成为可能.
- 通过使用圆盘形的超分子,成功制造了一种新型的光响应性器官凝.
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