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Published on: March 19, 2017
液晶"蓝色相"具有广泛的温度范围
Harry J Coles1, Mikhail N Pivnenko
1Centre of Molecular Materials for Photonics and Electronics, Engineering Department, University of Cambridge, Trumpington Street, Cambridge CB2 1PZ, UK. hjc37@cam.ac.uk
Nature
|August 19, 2005
概括
研究人员开发了新的液晶,其蓝色相具有广泛的温度范围,使可调节的光子晶体应用成为可能. 这些材料在电场中表现出可逆的色彩切换,克服了以前的限制.
科学领域:
- 材料科学 材料科学 材料科学
- 凝聚物质物理学 凝聚物质物理学
- 晶体学 晶体学是指结晶学.
背景情况:
- 蓝色相是具有光衍射特性的自组装立方液晶结构.
- 它们狭窄的温度范围 (0.5-2°C) 限制了作为可调节光子晶体的实际应用.
- 现有的蓝色阶段仅限于同otropic 和 chiral nematic (N*) 阶段之间.
研究的目的:
- 为蓝色相开发具有显著增强热稳定的液晶.
- 探索这些新材料在光子应用中的潜力.
- 调查观察到的宽蓝相稳定的基本机制.
主要方法:
- 光学纹理分析的方法
- 选择性反射光谱法选择性反射光谱法
- 科塞尔的图形图表
- 不同扫描热量计差异扫描热量计.
- 电光电池测量 电光电池测量
主要成果:
- 发现了一种新的液晶家族,表现出从60°C到16°C的宽体中心立方相 (BP I*).
- 在没有偏振器的电池中使用电场,在10毫秒内实现了可逆的广域色彩切换.
- 增强的稳定性归因于二维分子结构和高的柔电系数.
结论:
- 开发出来的液晶提供了稳定且广泛调节的蓝色相,克服了以前的热限制.
- 这些材料显示出先进光子应用的巨大潜力.
- 这些发现在液晶研究中提出了新的理论挑战和机遇.
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