平面奇拉循环以太:不对称的分辨率和奇拉性转换
Katsuhiko Tomooka1, Nobuyuki Komine, Daisuke Fujiki
1Department of Applied Chemistry, Graduate School of Science and Engineering, Tokyo Institute of Technology, Meguro-ku, Tokyo 152-8552, Japan. ktomooka@apc.titech.ac.jp
Journal of the American Chemical Society
|September 1, 2005
概括
稳定的平面奇拉性在一个九个成员的循环以太体中被发现. 这种新型的性构建块是使用动力分辨率合成的,产生一种以酶体丰富的化合物.
科学领域:
- 有机化学 有机化学
- 立体化学是一种立体化学.
背景情况:
- 平面性奇拉性是一种奇拉性,其中奇拉性来自于替代物围绕平面的排列.
- 循环乙烯是多功能化合物,在各种化学合成中具有应用.
研究的目的:
- 为了研究一种新的九个组成的二次循环乙烯的合成和特性.
- 探索这种化合物的潜力作为一种性构建块.
主要方法:
- 循环以太的racemic混合物的动力分辨率.
- 丰富酵素产品的特征. 丰富酵素产品的特征.
主要成果:
- 值得注意的是,在九个成员的二次循环中观察到非常稳定的平面性.
- 通过动态分辨率成功制备了聚丰富的以太.
结论:
- 合成的九个成员的二次循环以太表现出稳定的平面奇拉性.
- 这种化合物代表了有机合成的有价值的新型性构建块.
相关概念视频
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