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Synthesis and Performance Characterizations of Transition Metal Single Atom Catalyst for Electrochemical CO2 Reduction
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在硫酸上对n-butan的氧化激活

Xuebing Li1, Katsutoshi Nagaoka, Laurent J Simon

  • 1Lehrstuhl für Technische Chemie II, Technische Universität München, Lichtenbergstrasse 4, 85747 Garching, Germany.

Journal of the American Chemical Society
|November 17, 2005
PubMed
概括

硫酸酸通过首先形成烯来催化基转化. 这一过程涉及氧化脱,对于催化活性和失活都至关重要.

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All meta-directing substituents are deactivating groups. These substituents withdraw electrons from the aromatic ring, making the ring less reactive toward electrophilic substitution. For example, the nitration of nitrobenzene is 100,000 times slower than that of benzene because of the deactivating effect of the nitro group. The first step in an electrophilic aromatic substitution is the addition of an electrophile to form a resonance-stabilized carbocation. The energy diagrams for the...
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